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NotesESS HLTopic 6.4A natural ozone balance
Back to ESS HL Topics
6.4.54 min read

A natural ozone balance (ESS HL)

IB Environmental Systems and Societies • Unit 6

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Contents

  • The natural ozone balance at Higher Level
  • Ozone is made and broken down all the time
  • A steady state
  • Exam-style question
The natural ozone balance at Higher Level: The same balance as SL, with the chemistry written out: at HL you need the equations for ozone formation and destruction. Learn the four reactions here; the next micro adds the reactions by which human-made chemicals speed up the destruction.

Practise this as you read

  • Write the four equations of the cycle from memory.
  • Explain the steady state as equal rates of formation and destruction.

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Ozone is never finished: High in the stratosphere, sunlight makes ozone and sunlight breaks it down, every second of the day.

The points to remember

  • Made, step 1: high-energy UV splits an oxygen molecule (O₂) into two oxygen atoms.
  • Made, step 2: each oxygen atom joins an oxygen molecule to make ozone (O₃).
  • Broken, step 3: ozone absorbs UV and splits into an oxygen molecule and an oxygen atom.
  • Broken, step 4: an oxygen atom meets an ozone molecule, and they make two oxygen molecules.
  • Step 3 is how the ozone layer absorbs UV: the UV's energy is used to split the ozone.
HL: the equations: O₂ + UV → O + O

O + O₂ → O₃ (formation)

O₃ + UV → O₂ + O, and O + O₃ → 2 O₂ (destruction)
Diagram of the four reactions: O2 + UV gives O + O; O + O2 gives O3; O3 + UV gives O2 + O; O + O3 gives 2 O2; the first two add ozone, the last two remove it
The four reactions, with equations.
Remember it as: UV makes it, UV breaks it.

Real example: the steps above are the Chapman cycle (Sydney Chapman, 1930). Most ozone is made over the tropics, where the Sun's UV is strongest, and is then carried towards the poles.

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If ozone is made and destroyed all the time, why does the ozone layer not grow or vanish? Because the two processes run at the same rate.

The points to remember

  • Ozone is made and broken down at the same time, all the time.
  • When the two rates are equal, the amount of ozone stays about the same.
  • This is a steady-state equilibrium: things keep changing, but the total stays steady.
  • If ozone builds up, more of it is there to be broken down, so it falls back: a negative feedback.
  • So the concentration of ozone stayed about constant over long periods of time.

Inputs to the ozone store

  • UV splits oxygen molecules
  • Oxygen atoms join oxygen to make ozone

Outputs from the ozone store

  • Ozone absorbs UV and splits
  • Oxygen atoms and ozone make oxygen
Link 1.2: a steady state: Like a bath with the tap on and the plug out: if water flows in as fast as it drains, the level stays the same, even though the water is always changing.

Real example: in spring, ozone over Antarctica measured about 300 Dobson units from the 1950s into the 1970s, year after year: formation and destruction were in balance.

How this comes up: A short Paper 2 question on how ozone forms and breaks down, or why its amount stays steady. Give each step in order, one per mark.
IB-style questionOutline[4 marks]

In the stratosphere, ozone is made and destroyed by natural reactions driven by sunlight.

Using chemical equations, outline how ozone is formed and destroyed naturally.

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Satellites show that more ozone is made in the stratosphere above the tropics than anywhere else.

why most ozone is made above the tropics.
[2 marks]

Related ESS HL Topics

Continue learning with these related topics from the same unit:

6.1.1The atmosphere and its layers
6.1.2Uneven heating and global circulation
6.1.3Greenhouse gases and aerosols
6.1.4The natural greenhouse effect
View all ESS HL topics

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6.4.4Harm from ultraviolet radiation
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Ozone-depleting substances6.4.6

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