The pH scale and strong vs weak acids and bases
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Question
What is pH?
Answer
A measure of acidity based on hydrogen-ion concentration: $\text{pH} = -\log_{10}[\text{H}^{+}]$.
Question
Formula for pH?
Answer
$\text{pH} = -\log_{10}[\text{H}^{+}]$ — given in the data booklet.
Question
How do you get [H_{+}] from pH?
Answer
$[\text{H}^{+}] = 10^{-\text{pH}}$ — the rearranged given equation.
Question
What is K_{w}?
Answer
The ionic product of water, $K_{w} = [\text{H}^{+}][\text{OH}^{-}] = 1.0\times10^{-14}$ at 25 °C.
Question
Acidic, neutral or basic by pH?
Answer
pH < 7 acidic · pH = 7 neutral · pH > 7 basic (alkaline), at 25 °C.
Question
What does a change of 1 pH unit mean?
Answer
[H_{+}] changes by a factor of **10** (pH is a log scale).
Question
Strong vs weak acid?
Answer
Strong = **fully** dissociated into ions; weak = only **partially** dissociated.
Question
Does 'strong' mean 'concentrated'?
Answer
No — strength is the **degree of dissociation**; concentration is the amount dissolved.
Question
Dissociation equation for a strong acid?
Answer
Single arrow, e.g. $\text{HCl} \rightarrow \text{H}^{+} + \text{Cl}^{-}$ (full dissociation).
Question
Dissociation equation for a weak acid?
Answer
Equilibrium arrows, e.g. $\text{CH}_{3}\text{COOH} \rightleftharpoons \text{H}^{+} + \text{CH}_{3}\text{COO}^{-}$ (partial).
Question
How to tell a strong from a weak acid at equal concentration?
Answer
Strong acid has a **lower pH**, **higher conductivity** and a **faster** reaction (more H_{+} ions).
Question
Why does a strong acid have a lower pH than a weak acid of the same concentration?
Answer
It is fully dissociated, so it gives a **higher [H_{+}]**, and a higher [H_{+}] means a lower pH.
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Proton transfer reactions
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