Rate of reaction and collision theory
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All 12 Flashcards — Rate of reaction and collision theory
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Question
Define the rate of reaction.
Answer
The **change in concentration** of a reactant or product **per unit time**.
Question
What are the units of rate (followed by concentration)?
Answer
**mol dm⁻³ s⁻¹** — a concentration (mol dm⁻³) divided by a time (s).
Question
How do you find the rate from a concentration–time graph?
Answer
It is the **gradient** (steepness) of the curve — the tangent at a point gives the instantaneous rate.
Question
Why is a reaction fastest at the start?
Answer
The **reactant concentration is highest** at t = 0, so effective collisions are most frequent and the curve is **steepest**.
Question
Average rate vs instantaneous rate?
Answer
**Average** = total change ÷ total time (slope of the **chord**); **instantaneous** = slope of the **tangent** at one moment.
Question
What does collision theory state?
Answer
Particles must **collide** to react, but only **effective** collisions (enough energy + correct orientation) lead to a reaction.
Question
What two conditions make a collision effective?
Answer
Energy **≥ the activation energy Eₐ**, AND the particles collide in the **correct orientation**.
Question
Define activation energy, Eₐ.
Answer
The **minimum energy** that colliding particles must have for a reaction to occur.
Question
Why does a reaction slow down over time?
Answer
Reactants are **used up**, so their concentration falls and effective collisions become **less frequent**; rate drops to zero when reactants run out.
Question
Name two ways to follow the rate of a reaction that produces a gas.
Answer
Measure the **volume of gas** collected vs time, or the **mass lost** vs time.
Question
How do you measure the rate of a reaction that changes colour?
Answer
Use a **colorimeter** to measure the **light absorbed** as it changes with time.
Question
What is the initial rate, and how is it found?
Answer
The rate at t = 0 — the **slope of the tangent drawn at the start** of a concentration–time graph (the steepest point).
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Topic 5.2 hub
How fast? The rate of chemical change
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