Back to Topic 5.1 — How much? The amount of chemical change
5.1.5Chemistry SL12 flashcards

Titration and solution stoichiometry

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5.1.5
Question

What is a titration?

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All 12 Flashcards — Titration and solution stoichiometry

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Card 1definition

Question

What is a titration?

Answer

A precise technique to find an **unknown concentration** by reacting it with a **standard solution** to the **end point** (an indicator colour change).

Card 2definition

Question

What is a standard solution?

Answer

A solution of **precisely known concentration**, made up in a **volumetric flask**.

Card 3definition

Question

What does a pipette do in a titration?

Answer

Delivers a **fixed, exact** volume of the solution being analysed (e.g. 25.0 cm³).

Card 4definition

Question

What does a burette do in a titration?

Answer

Delivers the **variable** volume of titrant (the **titre**), read to ±0.05 cm³.

Card 5formula

Question

What is the formula linking amount, concentration and volume?

Answer

$n = CV$ — amount (mol) = concentration (mol dm⁻³) × volume (**dm³**). Given in the data booklet.

Card 6process

Question

What are the three steps of a titration calculation?

Answer

**(1)** n = CV on the known reagent → mol. **(2)** Cross by the **mole ratio**. **(3)** C = n/V (or M = m/n) on the unknown.

Card 7concept

Question

Why must the titre be converted before using n = CV?

Answer

The volume must be in **dm³** — divide a cm³ titre by **1000** first.

Card 8definition

Question

What are concordant titres?

Answer

Titres that **agree** (typically within 0.10 cm³). Only the concordant titres are **averaged** — a rough trial is ignored.

Card 9concept

Question

What is a back titration?

Answer

Add a **known excess** of a reagent, let it react, then titrate the **leftover** excess. Amount reacted = **added − leftover**.

Card 10concept

Question

When is a back titration used?

Answer

When the reaction is **slow** or the sample is an **insoluble solid** (e.g. a carbonate), making a direct titration impractical.

Card 11concept

Question

Mole ratio of NaOH to H_{2}SO_{4} in neutralisation?

Answer

**2 : 1** — sulfuric acid is diprotic, so it needs **two** moles of NaOH per mole of acid.

Card 12concept

Question

Commonest dropped mark in a titration calculation?

Answer

Forgetting the **mole ratio** from the balanced equation, or leaving a volume in **cm³** instead of dm³.

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