The ideal gas equation and molar volume
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Question
What is the ideal gas equation?
Answer
$PV = nRT$ — links pressure, volume, amount and temperature of an ideal gas.
Question
What is STP?
Answer
**Standard temperature and pressure**: 273 K (0 °C) and 100 kPa.
Question
What is the molar volume at STP?
Answer
V_{m} = **22.7 dm³ mol⁻¹** — the volume of one mole of any ideal gas at STP.
Question
Find moles of a gas at STP?
Answer
$n = \dfrac{V}{V_{m}}$ — divide the volume (in dm³) by 22.7.
Question
Find the volume of a gas at STP?
Answer
$V = n\,V_{m}$ — multiply the amount (mol) by 22.7 dm³ mol⁻¹.
Question
Units needed for PV = nRT?
Answer
**Pa** (pressure), **m³** (volume) and **K** (temperature), because R = 8.31 J K⁻¹ mol⁻¹ is in SI units.
Question
Value of the gas constant R?
Answer
R = **8.31 J K⁻¹ mol⁻¹** (given in the data booklet).
Question
Convert kPa to Pa?
Answer
**Multiply by 1000** — e.g. 101 kPa = 1.01 × 10⁵ Pa.
Question
Convert dm³ to m³?
Answer
**Divide by 1000** — e.g. 24.0 dm³ = 0.0240 m³.
Question
Convert °C to K?
Answer
**Add 273** — e.g. 25 °C = 298 K.
Question
STP shortcut vs PV = nRT — which when?
Answer
**At STP** use V_{m} = 22.7; at **any other conditions** use PV = nRT with SI units.
Question
Get molar mass from gas data?
Answer
Find n from PV = nRT, then $M = \dfrac{m}{n}$ using the sample mass.
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Topic 1.5 hub
Ideal gases
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